Thermodynamic Functions
(for vapor at 1 atm.)
| Temp (°K)
| -[F° - H°o / T] cal/deg.mole |
H° - H°o / T cal/deg.mole |
S° cal/deg.mole |
C°o cal/deg.mole |
H° - H°o cal/deg.mole |
| 298 |
46.33 |
9.42 |
55.76 |
11 |
2810 |
| 300 |
46.39 |
9.43 |
55.82 |
11.02 |
2830 |
| 350 |
47.87 |
9.69 |
57.54 |
11.47 |
3391 |
| 400 |
49.17 |
9.94 |
59.11 |
11.93 |
3976 |
| 500 |
51.44 |
10.42 |
61.84 |
12.68 |
5210 |
| 600 |
53.38 |
10.85 |
64.23 |
13.28 |
6511 |
| 700 |
55.09 |
11.21 |
66.31 |
13.76 |
7848 |
| 800 |
56.61 |
11.58 |
68.17 |
14.15 |
9263 |
| 900 |
57.99 |
11.89 |
69.86 |
14.51 |
10702 |
| 1000 |
59.29 |
12.15 |
71.4 |
14.84 |
12153 |
| 1100 |
60.43 |
12.41 |
72.83 |
15.15 |
13656 |
| 1200 |
61.56 |
12.65 |
74.17 |
15.45 |
15186 |
| 1300 |
62.52 |
12.87 |
75.41 |
15.72 |
16737 |
| 1400 |
63.5 |
13.09 |
76.58 |
15.97 |
18322 |
| 1500 |
64.41 |
13.29 |
77.69 |
16.2 |
19935 |
P.A. Giguere, I.D. Liu, J.S. Dugdale, J.A. Morrison. Can. J. Chem., 74:3715 (1952)
Notes:
Cpo = constant pressure heat capacity
Fo = free energy
Hoo = enthalpy at absolute zero
T = absolute temperature
Ho = enthalpy of H2O2 as ideal gas at 1 atmosphere