Standard Electrode Potentials
H2O2 contains oxygen in a state of oxidation midway between molecular oxygen and water.
| Oxygen Moiety |
Reduction → |
| O2 ↔ H2O2 ↔ H2O |
| Oxygen Valence |
|
| ← Oxidation |
| H2O2 → O2 + 2H+ + 2e- |
Eo = -0.682 V |
| H2O2 + 2H+ + 2e- → 2H2O |
Eo = 1.776 V |
For perhydroxyl ion (HO2-):
| OH- + HO2- → O2 + H2O + 2e- |
EBo = 0.084 V |
| 3OH- → HO2- + H2O + 2e- |
EBo = -0.87 V |