H2O2 Related Electrochemical Values

Potential, Volts
HO2 + H+ + e- ↔ H2O2 1.5
O2 + H2O + 2e- ↔ HO2- + OH- -0.076
O2 + 2H2O + 2e- ↔ H2O2 + 2OH- -0.146
HO2- + H2O + 2e- ↔ 3OH- 0.87

Heat for formation (Δ Hfo) for:

HO. 9.2 ± 1 kcal/mole Ref: J.A. Kerr, Chem.Rev. 66:465 (1966)
HO2- 5.3 ± 2 kcal/mole Ref: J.A. Kerr, Chem.Rev. 66:465 (1966)

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